The a(3Π0+, 3Π1) → X1Σ+ visible band systems of boron monoiodide, BI
DOI: 10.1016/0009-2614(85)80209-8
Title: The a(3Π0+, 3Π1) → X1Σ+ visible band systems of boron monoiodide, BI
Journal Title: Chemical Physics Letters
Volume: 117
Issue: 3
Publication Date: 14 June 1985
Start Page: 229
End Page: 234
Published online: online 28 November 2001
ISSN: 0009-2614
Affiliations:
  • Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada B3H 4J3
  • Abstract: 0+, 1) → X1Σ++ band systems of BI, excited by the reaction of discharged helium with BI3, have been recorded photoelectrically at low resolution. 33 P-heads of the a(0+) → X systems of 10Bl and 11Bl, and 15 P, Q-heads of the a(1) → X system of 11BI have been measured and vibrationally assigned. The data for the a(0+) → X system extend considerably the results of an earlier investigation; the a(1) → X system is observed for the first time. The head positions have been fitted simultaneously by least squares to obtain estimates of the vibrational constants of the three states.
    Received: 27 February 1985

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